Mehdi Teymouri., Marcelo Sánchez and J. Carlos Santamarina (2020). A pseudo-kinetic model to
simulate phase changes in gas hydrate bearing sediments, Marine and Petroleum Geology
Abstract
Modeling of the phase transitions anticipated in gas hydrate bearing sediments (GHBS) is critical for a
31 proper understanding of time-dependent changes in states and volumes (e.g. the production of methane
32 from this type of soils). We propose a new pseudo-kinetic approach to simulate the typical phase changes
33 anticipated in GHBS, using published experimental results involving gas hydrate dissociation that are the
34 basis of a widely used kinetic model. The proposed pseudo-kinetic model is formulated in the pressure35 temperature (P-T) plane and assumes a rate of gas hydrate dissociation (or formation) proportional to the
36 distance between the current state and the phase boundary. The model consists of only one parameter and
37 is simple to implement in numerical simulators. A similar concept is used to model ice formation/thawing
38 phenomena, but based on the ice/liquid-water phase boundary. We implemented the pseudo-kinetic model
39 in a fully coupled thermo-hydro-chemo-mechanical (THCM) finite element code and validated it against
40 experimental results performed on the dissociation of synthetic gas hydrate. We also evaluated the
41 pseudo-kinetic model using synthetic cases covering several scenarios associated with gas hydrate
42 formation/dissociation and ice formation/thawing. The model successfully reproduced the gas production
43 test from a natural GHBS core from Korea (scaled gas venting experiment over 14hours), and also the
formation of gas hydrate and ice in permafrost in Alaska (over 2x106
44 years). We show the versatility of
45 the proposed approach by applying it to model the different phase transitions typically encounter in
46 GHBS. The simple formulation, easy implementation in numerical simulator, and reduced number of
47 parameters (only one per phase change) make this model an attractive option for simulating phase
48 transformations in problems involving GHBS.
Keywords
gas hydratehydrate dissociationhydrate formationice formation/meltingphase transitionsnumerical modelingvalidation